Article as seen in Circuitree Magazine,
July 1996, by John S. Eddy, President and Co-founder of Eddy Electronics
Mfg. Ltd.
With environmental concerns and increasing regulations on industrial
pollution, lead is looming large as a major problem for the PCB and
electronics industry.
Environmental problems are compounded by
widely differing and uneven environmental regulations and practices
across the globe that have led to political and financial obstacles for
our industry.
Most PCB manufacturers live with some fear
that the consequences of these practices could overtake them suddenly in
some change in law or environmental policy.
As a conscientious industry in the
developed world, PCB manufacturers are already pursuing ways to reduce
lead consumption in our industry and with the threat of unfair offshore
competition, it is of even greater concern. If lead in electronic
products can be reduced, we can also reduce the threat of lost
contracts, jobs, and competitiveness. If lead consumption is to be
reduced, PCB manufacturers can benefit the most by leading the way.
There has been much development in lead
free solders and interconnects. Conductive ink has been promoted for
years but has failed to gain broad acceptance, especially as a
replacement for copper traces. Indium solders show great promise but are
very costly. Tin-bismuth solders are considered safe but oxidize easily
and lack ductility. Even if there is no immediate replacement for
tin-lead solder, there is considerable interest in replacing it. Wave
solder machines, their fumes and waste materials are considered health
and safety hazards.
Perhaps the greater impact on the
consumption of lead is not in the soldered connections, but rather in
the printed circuit itself. The processes required for putting lead on
the printed circuits are inefficient and, in themselves, present
occupational hazard and waste treatment problems that are out of all
proportion to any value they add.
A promising new development now exists in
Canada where Eddy electronics Mfg. Ltd has developed a manufacturing
process which is lead-free. Standard and non-value adding process steps
have been abandoned and only simpler and cleaner steps are in place.
Manufacturing starts in a very
conventional way with the normal drilling and electroless copper. Then,
Eddy Electronics panel plates the copper to the specified thickness in a
pyrophosphate bath. Pyrophosphate is preferred for its ductility and
strength. Lamination and imaging follow to produce a "tent and etch"
bare copper printed circuit. The last wet process step is an efficient
immersion silver bath which is self regulating and produces a layer 2-4
microns thick. Solder mask and overlay are of course normal, and the
silver provides excellent adhesion with a low profile relative to solder
plated PCBs.
The cost of waste management is far less
in the absence of lead. Hot Air Solder Leveling, once favored for low
solder profile and relative cleanliness, has been identified by the
October Project consortium as a process to be eliminated.
This process offers other advantages
including: Copper bearing waste is free of lead and recycling can
proceed on-site at a PCB plant. Phototool film with its silver emulsion
can be used as a valuable resource rather than a waste treatment
problem.
High quality PCBs are manufactured with
this process that are comparable to common SMOBC types with the added
benefit of wide design latitude. Very fine features and very large
copper areas can be manufactured reliably with no concern for plating
densities or warpage. Eddy Electronics has manufactured PCBs with .003
lines and .004 spaces.
As the only solder on the finished product
is applied by the assembler, many different combinations of solder or
conductive ink may be used. Tin-lead solder may also be used. The low
profile nature of the product allows accurate placement of solder pastes
for SMD applications.
Eddy Electronics' product is a little
different but has been gaining acceptance in local and export markets
for more than ten years. Many similar approaches to the same end exist
and are under development. Organic coatings, like Entech, and various
electroless and immersion coatings have emerged over the past few years.
With future environmental sensibilities, acceptance of all of these
approaches are likely to grow.
A lead-free printed circuit allows
manufacturers to choose solders or bonding systems according to their
own criteria and makes a lead free electronic product a viable option.
Even if lead free is not the way they choose to go, the benefits ot PCB
fabricators can hardly be ignored.